SYNTHESIS AND STRUCTURAL ANALYSIS OF A Cu(II) COMPLEX WITH PYRIDOXAL S-METHYLISOTHIOSEMICARBAZONE (PLITSC) LIGAND

S.  Ivković; V.  Jevtović

SYNTHESIS AND STRUCTURAL ANALYSIS OF A Cu(II) COMPLEX WITH PYRIDOXAL S-METHYLISOTHIOSEMICARBAZONE (PLITSC) LIGAND

Authors

S. Ivković Faculty of Environmental governance and corporate responsibility, University EDUCONS,Sremska Kamenica, Serbia
V. Jevtović Department of Chemistry, Faculty of Sciences, University of Novi Sad, Serbia

Keywords:

Pyridoxal-S-methylisothiosemicarbazone, Cu(II) complex, Synthesis, Crystal structure

Abstract

Reaction between a warm water mixture of pyridoxal hydrochloride (PL.HCl), and Smethyilisothiosemicarbazidehydroiodide (SMeTSC.HI) in the presence of Na₂CO₃ .10 H O, we got pyridoxal S-methylisothiosemicarbazone (PLITSC; H₂L). Ligand with appropriate Cu salt is coordinated, to give next complex: dark-brown, penta coordinated, square-pyramidal structure, mono(ligand)complex Cu(II) formula, [Cu(PLITSC)Br(CH₃OH)]Br.In this work is given synthesis and structure of the complex with Schiff-based ligand.

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Published

2010-12-31

How to Cite

Ivković, S. ., & Jevtović, V. . (2010). SYNTHESIS AND STRUCTURAL ANALYSIS OF A Cu(II) COMPLEX WITH PYRIDOXAL S-METHYLISOTHIOSEMICARBAZONE (PLITSC) LIGAND. Journal of Engineering &Amp; Processing Management, 2(2), 7–13. Retrieved from http://jepm2021.tfzv.ues.rs.ba/index.php/pub/article/view/49